Li will hold meetings with Thai Prime Minister Prayut Chan-o-cha, and join him in witnessing the signing of cooperation documents and meeting the press.
Li said that 25,000 companies from home and abroad will promote their products online and live video marketing and cross-border e-commerce services will be available to all companies and overseas buyers.
Lian Ping, chief economist with the Bank of Communications, has said the suspensions did not point to tightened monetary policy.
Li was at the cornerstone-laying ceremony when Intel Dalian began construction in the city a decade ago. He was serving as Party secretary of Liaoning province at the time.
Li's trip will be the first time in nearly three years that a member of the Standing Committee of the Political Bureau of the CPC Central Committee has visited Pyongyang.
Li underscored the importance of establishing stringent oversight mechanisms to ensure that the funds are put to good use.
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Li said in addition to "patient communications" with them, over 1,200 patents Nio has developed and more than 800,000 swaps done over the years helped to persuade them.
Li made the remarks in a meeting with Yohei Kono, president of the Japanese Association for the Promotion of International Trade (JAPIT), and a business delegation led by Kono at the Great Hall of the People in Beijing.
Li said China values the friendly ties with these countries, remains committed to the path of peaceful development, mutual respect and win-win cooperation, and sticks to the principles of multilateralism, as well as trade and investment liberalization and facilitation.
Lia Zhu in San Francisco contributed to this story.